Should I Order Syndication Networks First Before RYS Stacks?

In episode 249 of our weekly Hump Day Hangouts, one viewer asked if one should order syndication networks first before RYS stacks.
The exact question was:
I'm in the Syndication 2.0 training. WOW, tons of great info. I don't think I want to put one together though. Would I order that first prior to the RYS stack?
